Theres alot of competition with PHP as it is very popular.
You've got to put alot of work into making yourself known and keeping your clients happy. Its sometimes hard, but if you think you could manage it, give it a go.
As a Freelancer, I think it would be more beneficial to learn PHP first and then move on to something like c# .NET. Whether this is the best option or not, I'm not too sure, but I'll think I'll give it a shot.
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